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Federal Highway Administration Research and Technology
Coordinating, Developing, and Delivering Highway Transportation Innovations

Report
This report is an archived publication and may contain dated technical, contact, and link information
Publication Number: FHWA-HRT-07-039
Date: July 2007
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Appendix B - Corrosion Resistant Alloys for Reinforced Concrete

EXAMPLE CALCULATION OF CORROSION RATE FROM POLARIZATION RESISTANCE

Corrosion rate, CR, was calculated from the measured polarization resistance, PR, using a modified form of the Stern-Geary equation,

Modified form of the Stern-Geary equation expressing the inverse relationship between corrosion rate and polarization resistance. Corrosion rate equals 3.15 times 10 to the power of seven; that times the quotient of the atomic weight of the corroding metal divided by the product of the number of electrical equivalents, Faraday’s constant, and metal density; that times the quotient of a term that depends on the Tafel constant divided by the measured polarization resistance.
(3.2)

where Z is atomic weight, n is the number of electrical equivalents, F is Faraday’s constant, ρ is alloy density, and B is a term the value for which depends on the Tafel constants. For the case of black bar reinforcing steel, a typical measured value for PR was 103 Ω·cm2. Thus, with values for the other constants as,

Z = 56 grams/mol,
n = 2 equivalents,
F = 96,500 Coulombs/mol·equivalent,
ρ = 7.87 grams/cm3, and
B = 0.026 V,
appendix b
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